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2017-07-28 09:18:50 -0600 answered a question Python Load OpenCV FileStorage

Conventions in OpenCV 3.2 seem to be a little different to the other answers. I've used this with success:

import cv2
fs = cv2.FileStorage("calibration.xml", cv2.FILE_STORAGE_READ)
fn = fs.getNode("Camera_Matrix")
print (fn.mat())