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Are you certain that the folder you added to the system path contains the required dll's ?
My easy setup: I have added a DLL folder in my C;\, and added to it every version of the opencv dll's (release and debug, win32 and x64); I have added a system environment variable pointing to that c:\DLL folder.
As for the errors in your comment, they seem to indicate missing lib... so check the Additional Dependencies, under Linker-> Input.
It may be easier (to change, to read...) if you place these dependencies in a property sheet as well.
