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I recommend using homebrew to install OpenCV and its dependencies if you are not too familiar with building them manually. OpenCV 2.4.7 is able to build without Cuda just fine on Mavericks currently. Most likely you experienced problems due to some of OpenCV's dependencies being built against libstdc++, while OpenCV and your being built against libc++ (the new default on Mavericks). This is solved by rebuilding OpenCV and all of its dependencies after upgrading.